Organosilicon Chemistry_ From Molecules to Materials [Volume VI]

Organosilicon Chemistry_ From Molecules to Materials [Volume VI]期刊合订本 正文1000页


Edited by Norbert Auner and Jo hann Weis

published by Wiley-VCH

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正文提纲

Chapter I
Organosilicon-Based Reactive Intermediates
Learning from Silylenes and Supersilylenes ...................................................................................... 10
Gaspar, P. P,
Kira, Ad; Iwumoto, T.; Ishida, S.
1- [2,6-Bis(dimethylaminomethyl)phenyl]-2,2-bis(~imethylsilyl)silene-s Syntheses, Structures,
and Reactions ..................................................................................................................................... 33
Baumer, U.; Reinke, H ; Oehme, H.
Quantum Chemical DFT and Experimental Study of ortho-, metha-, and para-Toiyl-Substituted
Methylsilene Rearrangements ............................................................................................................ 37
Guselnikov, S. L.; Volkova, V. V.; Avakyun, V. G.; Gusel 'nikov, L. E.
Toulokhonova, I.; Stringfellow, T. C.; West, R.
Kinetic Stabilization of Polysilyl Radicals ........................................................................................ 48
Kravchenko, V.; Bravo-Zhivotovskii, D.; Tumanskii, B. ; Botoshansky, M.; Segal, N.; Molev, G.;
Kosa, M ; Apeloig, Y.
Out-of-Range 629Si Chemical Shifts of Diaminosilylenes - an ab initio Study ............................. 59
Flock, M.; Dransfld, A.
Comparison of Heterocyclic Diaminosilylenes with Their Group 14 Homologs .............................. 64
Heinicke, J.; Kiihl, 0.
Spectroscopic Evidence for the Formation of the Pentamethylcyclopentadienylsilicon Cation ....... 69
Jutzi, P.; Mix, A.; Rummel, B.; Neumunn, B.; Stammler, If.-G.; Rozhenko, A,; Schoeller, K K
Synthesis and Characterization of Bissilylated Onium Ions of Group 15 Elements ......................... 74
Panisch, R.; Mullet-, T.
Structural and Spectroscopic Evidence for j3-Sic Hyperconjugation in Vinyl Cations .................... 80
Miiller, T.; Juhasz, M ; Reed, C. A.
Tertiary Trisilyloxonium Ion and Silylenium Cation in Cationic Ring-Opening Polymerization
of Cyclic Siloxanes ............................................................................................................................ 85
Cypryk, M ; Chojnowski, J.; Kurjata, J.
New Molecular Systems with Silicon-Silicon Multiple Bonds ........................................................ 25
A I ,4-Disilapentalene and a Highly Stable Silicon Diradical ............................................................ 43
X Contents
Chapter I1
Molecular Inorganic Silicon Chemistry
Dihalodimethylsilanes from Silicon Atoms and Methyl Halides ...................................................... 94
Reactions of Silicon Atoms with Amines and Phosphine under Matrix Isolation Conditions ........ 101
Maier, G.; Glatthaar, J.; Reisenauer, H. P.
Maier, G.; Glatthaar, J.; Reisenauer, H. P.
New Insights into the Halophilic Reaction of a Stable Silylene with Halocarbons: A Matrix -
Spectroscopic Study ......................................................................................................................... 107
Glatthaar, J.; Maier, G.; West, R.
Compensation Effect in Direct Reactions of Silicon ....................................................................... 112
Acker, J.; Lieske, H ; Bohmhammel, K.
On Reasons for Selectivity Losses in TCS Synthesis ...................................................................... 119
Kiirschner, U.; Radnik, J.; Lieske, H.; Hesse, K.; Pdtzold, U.
Characterization of Trichlorosilane Direct Process Residue ........................................................... 126
Harder, P. J.; Tselepis, A. J.
Dichlorosilylene Transfer Reactions Using Me3GeSiC13 ................................................................ I3 1
Seppala, E.; Gust, T.; Wismach, C.; du Mont, K-W.
Synthesis of B-Alkylsilylborazines by Rhodium-Catalyzed Hydroboration of
N-Alkylborazines ............................................................................................................................. 136
Lehnert, C.; Roewer, G.
Hydrosilylation of Ethynylborazines and Their Use for the Formation of a Highly
Functionalized Silica Gel ................................................................................................................. 142
Haberecht, J.; Riiegger, H.; Nesper, R.; Grutzmacher, H.
Influence of the Tri(tert-buty1)silyl Substituents on the Molecular Structures
of Phosphanylalanes, -gallanes and -indanes ................................................................................... 148
Weinrich, S.; Krojia, M ; Schulz, A.; Westerhausen, A4
Trifluoromethyl Silicon Compounds with Geminal Nitrogen Donor Centers ................................. 156
VojinoviC, K.; Mitzel, N. W.; Korth, M ; Frohlich, R.; Grimme, S.
Alkali Metal Cyantrimethylsilylamides - MWCNSi(CH&] ........................................................ 160
Kroke, E.
Amination in Supercritical Ammonia - Continuous Production of Aminoalkylsilanes ................ 167
Bauer, A.; Weis, J.; Rauch, J.
Mono- and Bis(hydroxy1amino)silanes - Reactions, Rearrangements, and Structures ................. 170
Ebker, C.; Diedrich, F.; Klingebiel, U.
From Silyldiamines to Mono-NH-SiF-functional Cyclodisilazanes - Synthesis, Reactions, and
Crystal Structures ............................................................................................................................. 177
Reiche, C.; Klingebiel, U.
Contents X I
From Lithium Halogenosilylamides to Four- and/or Fourteen-Membered Rings and New
14n-Electron Systems ...................................................................................................................... 182
Wand, A.; Kucharski, S.; Klingebiel, U.
Silyl-Enolethers and -Ethers - New Results of Keto-Enol Tautomerism ...................................... 188
Biischen, T.; Klingebiel, U.
“Hypervalent” Molecules - Low-Valency Candidates for Materials? .......................................... 194
Karsch, H. H,;Se gmiiller, T.
Strong Evidence for an Unconventional 1,2-(C+P)-Silyl Migration: Formation and Reactions
of a P-Silyl Phosphaalkene Complex ............................................................................................... 202
Ionescu, E.; Wilkens, H.; Streubel, R.
Strong Evidence for an Unconventional 1 ,2-(C+P)-Silyl Migration: DFT Structures and Bond
Strengths (Compliance Constants) .................................................................................................. .209
von Frantzius, G.; Grunenberg, J.; Streubel, R.
Silyl Group Migrations between Oxygen and Nitrogen in Aminosiloxanes .................................. 216
Kliem, S.; Klingebiel, U.
Terphenyl Phosphanosilanes ............................................................................................................ 222
Pietschnig, R.; Tirrke, J. J.
Hassler, K. ; Tekautz, G.; Baumgartner, J.
Homo- and Heterometallic Bismuth Silanolates .............................................................................. 233
Mehring, M ; Mansfel4 D.; Nolde, C.; Schiirmann, M
The Effect of Silyl Anion Substituents on the Stability and NMR Characteristics of Cyclic
Polyphosphines - an ab initiolNMR Study ................................................................................... 240
Dransfeld, A.; Hassler, R
Silanols as Precursors to Cyclo- and Polysiloxanes ........................................................................ 245
Veith,M ; R ammo, A.; Schutt, F. 0.S;p aniol, P. P.; Huch, K
The Origin of Ring Strain and Conformational Flexibility in Tri- and Tetrasiloxane Rings and
Their Heavier Group 14 Congeners ................................................................................................. 252
Beckmann, J.; Dakternieks, D.; Lim, A. E. K.; Lim, R F.; Jurkschat, K
29Si NMR Chemical Shift Tensors in Organosilicon Chalcogenides .............................................. 259
Herzog, U.; Bohme, U.; Brendler, E.
Hypersilyltelluro-Substituted Silanes and (Ph2SiTe)s ...................................................................... 265
Lange, H.; Herzog, U.; Roewer, G.; Borrmann, H.
Novel Dimeric Pentacoordinate Silicon Complexes: Unusual Reactivity of Electron-Rich
Aminosilane Intermediates .............................................................................................................. 27 1
Dona, N.; Men, K.; Driess, M
Unique Switching of Coordination Number with Imine and Enamine Complexes of
Group 14 Elements .......................................................................................................................... 279
Wagler, J.; Bohme, U.; Roewer, G.
Preparations and X-Ray Structures of some Silicon-Phosphorus and Silicon-Arsenic Cages ........ 228
XII Contents
Structures of Novel Diorgano-Substituted Silicon Complexes with Hexacoordinate
Silicon Atom .................................................................................................................................... 285
Roewer, G.; Wagler, J.
Novel Hypercoordinate Silicon Complexes from Silicon Tetrahalides and Bidentate <O,N>
Donor Ligands ................................................................................................................................. 29 1
Schley, M ; Bohme, U.; Roewer, G.; Brendler, E.
Steric Effect on the Formation, Structure, and Reactions of Pentacoordinate Siliconium
Ion Salts ........................................................................................................................................... 297
Kalikhman, I.; Gostevskii, B.; Sivaramabishna, A.; Kost, D.; Kocher, N.; Stalk, D.
Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(1V)
Complexes with SiO2N4 Skeletons .................................................................................................. 303
Seiler, 0.; Fischer, M; Penka, M.; Tach, R.
Vinyloligosilyl Anions - a New Class of Compounds .................................................................. 309
Markov, J.; Baumgartner, J.; Marschner, C.; Oehme, H.; Gross, T.
Oligosilyl- 1,2-dipotassium Compounds: a Comparative Study ...................................................... 3 14
Fischer, R.; Konopa, T.; Baumgartner, J.; Marschner, C.
Heteroatom-Substituted Silyl Anions .............................................................................................. 3 19
Fischer, R.; Likhar, P. R.; Baumgartner, J.; Marschner, C.
Reactions of Hypersilyl Potassium with Rare Earth Bis(trimethylsily1amides): Addition Versus
Peripheric Deprotonation ................................................................................................................ .323
Niemeyer, M
Synthesis of Organosilicon Polymers from Silyl Triflates and (Aminosily1)lithium Compounds .. 330
Uhlig, W.
Polyhydroxyoligosilanes - Synthesis, Structure, and Coordination Chemistry ............................ 337
Krempner, C.
Synthesis, Structure, and Reactivity of Novel Bidentate Metal Disiloxides ................................... 344
Krempner, C.; Reink, H.; Weichert, X
Electronic Excitation in Decamethyl-n-tetrasilane ......................................................................... .348
Piqueras, M C.; Crespo, R.
Preparation and Structural Studies on Cyclohexasilane Compounds .............................................. 355
Fischer, R.; Konopa, T.; Uly, S.; Wallner, A.; Baumgartner, J.; Marschner, C.
Synthesis and Photoluminescence of Cyclohexasilanes Bearing Siloxyand
Amino Side Groups ................................................................................................................... 341
Stuger, H.; Fuvass, G.; Renger, K.
Conformational Properties of 1,1,2,2-Tetrakis(trirnethylsilyl)disiIanes and of Tetrakis-
(trimethylsily1)diphosphine: a Comparative Vibrational Spectroscopic and ab initio Study .......... 368
Tekautz, G.; Hassler, K.
Reactions of Octasilacubane ............................................................................................................ 373
Unno, M ; Matsumoto, H.
Contents XIII
Chapter I11
Transition Metals in Organosilicon-Based Chemistry
Transition Metals in Organosilicon Chemistry ................................................................................ 382
Tilley, T. D.
Hydrosilation (or is it Hydrosilylation?): A Personal Perspective on a Scientifically and
Technologically Fascinating Chemical Methodology ..................................................................... 392
Harrod, J. F.
DFT Calculations on the Activation of Silanes by Platinum Complexes with Hemilabile P,N
Ligands ............................................................................................................................................. 399
Sturmayr, D.; Schubert, U.
Hydrosilylation of Ethylene, Cyclohexene, and Ally1 Chloride in the Presence of Pt(0)
and Pt(2) Catalysts ........................................................................................................................... 404
Chernyshev, E. A.; Belyakova, Z. V.; Knyazev, S. P.; Storozhenko, P. A.
Synthesis of Glycidoxypropyl-Silanes and -Siloxanes via Rhodium Siloxide-Catalyzed
Hydrosilylation ................................................................................................................................ 408
Maciejewski, H.; Marciniec, B.; Blazejewska-Chadyniak, P.; Dqbek, I.
New Functionalization of Vinyl-Substituted Organosilicon Compounds
via Ru-Catalyzed Reactions ............................................................................................................. 4 16
Marciniec, B.; Itami, K; Chadyniak, D.; Jankowska, M
Hydrosilylation Using Ionic Liquids ............................................................................................... 424
Weyershausen, B.; Hell, K.; Hesse, U.
Baumann, F.; List, T.
[2+2]-Cycloadditions of (OC)4Fe=SiMez - Theoretical Study ..................................................... 438
Bohme, U.
Ho&ann, K ; Bohme, U.; Roewer, G.
Cp-Free Hafnium Silyl Substituted Compounds ............................................................................. 452
Frank, D,; Baumgartner, J; Marschner, C.
Bera, H.; Schmitzer, S.; Schurnacher, D. ; Malisch, W.
Sohns, A.; Schumacher, D.; Malisch, W.; Nieger, M
Synthesis and Reactivity of Polychlorinated Metallo-Siloxanes ..................................................... 468
Schumacher, D.; Malisch, W.; Soger, N.; Binnewies, M
Bera, H.; Sohns, A.; Malisch, W.
On-Line FT-Raman Spectroscopy for Process Control of the Hydrosilylation Reaction ................ 432
Reactions of Undecamethylcyclohexasilyl-potassiumw ith Transition Metal Compounds ............4 45
Metal- and Cyclopentadienyl-Bound Silanol Groups in Tungsten Complexes ............................... 457
Half-Sandwich Iron Complexes with a Silanol-Functionalized Cyclopentadienyl Ligand ............. 462
Half-Sandwich Tungsten Complexes with Silyl-Functionalized q5-Cyclopentadienyl Ligand ...... 474
XIV Contents
Chapter IV
Silicon in Organic and Bioorganic Chemistry
Norbornylsilanes: New Organosilicon Protecting Groups .............................................................. .482
Heldmann, D. K.; Stohrer, J.; Zauner, R.
Synthesis and Reactivity of an Enantiomerically Pure N-Methyl-2-Silyl-Substituted Pyrrolidine ........................................................................................................................................ 488
Strohfeldt, K ; Seibel, T.; Wich, P.; Strohmann, C.
Diastereomerically Enriched a-Lithiated Benzylsilanes ................................................................ .495
Schildbach, D.; Bindl, M.; Hornig, J.; Strohmann, C.
An Enantiomerically Enriched Silyllithium Compound and the Stereochemical Course of its
Transformations ............................................................................................................................... 502
Hornig, J.; Auer, D.; Bindl, M ; FraaJ, V. C.; Strohmann C.
Reactions of CF3Si(CH3)3 and C6FsSi(CH3)3 with Perfluoroolefins and Perfluoroimines .............. 508
Nishida, M ; Hayakawa, 1; Ono, T.
Bis(trimethylsi1yI)mercury: a Powerful Reagent for the Synthesis of Amino Carbenes ................. 515
Otto, M ; Rudzevich, V.; Romanenko, V. D.; Bertrand, G.
Electrochemical Synthesis of Functional Organosilanes ................................................................ .522
Loidl, B.; Grogger, Ch.; Stiiger, H.; Pachab, B.; Weidner, R.; Kammel, T.; Bauer, A.
Photoluminescence and Photochemical Behavior of Silacyclobutenes .......................................... .527
Yan, D.; Hem A. A.; Auner, N.; Thomson, M ; Backer M
Tris- and Tetrakis-[oligo(phenylenevinylene)]-silanes: Synthesis and Luminescence Behavior .... 534
Detert, H.; Sugiono, E.
Synthesis, Luminescence, and Condensation of Oligo(phenyleneviny1ene)s with
Alkoxysilane End Groups ................................................................................................................ 539
Detert, H.; Sugiono, E.
How to Make Disilandiyl-Carbon Hybrid Materials: the First ADMET Metathesis Reactions of
Organodisilanes ............................................................................................................................... .546
Mera, G.; Driess, M
Application of a,o-Bis(dimethylvinylsi1oxy)alkanes ...................................................................... 553
PawluC, P.; Gaczewsku, B.; Marciniec, B.
Synthesis and NMR Spectra of Diaryl- and Dihetarylsilacycloalkanes .......................................... 559
Ignatovich, L.; Popelis, J.; Lukevics, E.
Synthesis and Biological Activity of Silicon Derivatives of 2-Trifluoroacetylfuran and Their
Oximes ............................................................................................................................................. 563
Ignatovich, L.; Zarina, D.; Shestakova, I.; Germane, S.; Lukevics, E.
Silicon Diols, Effective Inhibitors of Human Leucocyte Elastase ................................................... 569
Showell, G. A.; Montana, J. G.; Chadwick, J. A.; Higgs, C.; Hunt, H. J.; MacKenzie, R. E.; Price,
S.; Wilkinson, T. J.
Contents XV
0 Ligands of the 1,4‘-Silaspiro[tetralin- 1,4‘-piperidine] Type and the SerotoninlNoradrenaline
Reuptake Inhibitor Sila-venlafaxine: Studies on C/Si Bioisosterism .............................................. 575
Dag, J. 0.M; iiller, B.; Burschka, C.; Tacke, R.; Bains, W.; Wameck,J .
Possible Mechanisms of the Stimulating Effects of Isopropoxygermatran and 1 -Ethoxysilatran
in Regenerated Liver ........................................................................................................................ 582 Voronkov, M G.; Muhitdinova, H. N.; Nurbekov, M K.; Rasulov, M M ; D ’yakov, V. M
Wound Healing Effects of some Silocanes and Silatranes .............................................................. 588 D’yakov, V. M ; Voronkov, M G.; Kazimirovskaya, V. B.; Loginov, S. V.; Rasulov, M M
The Development of Methods of Synthesizing Organic Derivatives of Silicon Based on
Biogenic Silica ................................................................................................................................. 595 Ubaskina, J.; Ojtserov, Y.
Chapter V
Organosilicon Compounds for Industrial Applications
Silicon Science and Technology - an Industrialist’s View of the Future ...................................... 602
White, J. W.
The Markets for Silicones ................................................................................................................ 610
De Poortere, M
Synthesis of Organofunctional Polysiloxanes of Various Topologies ............................................. 620 Chojnowski, J.
A Facile Synthetic Route to Phosphazene Base Catalysts and Their Use in Siloxane Synthesis .... 628 Hupfild, P. C.; Surgenor, A. E.; Taylor, R. G.
Supramolecular Chemistry and Condensation of Oligosiloxane-cL,w-Diols HOSiMe2O(SiPh20),SiMezOH (n = 1 - 4) ..................................................................................... 635 Beckmann, J.; Dakternieks, D.; Duthie, A.; Foitzik, R. C.; Beckmann, J.
The Reactivity of Carbofunctional Aminoalkoxysilanes in Hydrolytic and Reetherification
Reactions .......................................................................................................................................... 641
Kovyazin, V. A.; Kopylov, V. M ; Nikitin, A. V.; Knyazev, S. P.; Chemyshev, E. A.
Study of Octyltriethoxysilane Hydrolytic Polycondensation ......................................................... .646 Plekhanova, N. S.; Kireev, V. V.; Ivanov, V. V.; Kopylov, V. M.
A Study of the Dependence of Silicone Compositions on the Initial Structure and Composition
of Oligoorganosiloxanes .................................................................................................................. 655 Nanushyan, S. R,; Alekeeva, E. I.; Polivanov, A. N.
Study of Rheological Properties of Oligoethylsiloxane-Based Compositions ................................ 66 1
Gureev, A. 0.; Koroleva, T. V.; Lotarev, M B.; Skorokhodov, I. I.; Chemyshev, E. A.
Silacyclobutene-PDMS Copolymers - Siloxanes with Unusual Thermal Behavior .................... .668 Backer, M. W.; Hannington, J. P.; Davies, P. R.; Auner, N.
Electrochemically Initiated “Silanone Route” for Functionalization of Siloxanes .......................... 675 Keyrouz, R.; Jouikov, V.
XVI Contents
Monofunctional Silicone Fluids and Silicone Organic Copolymers ............................................... 682
Keller, W.
Tailoring New Silicone Oil for Aluminum Demolding ................................................................... 687
Olier, P.; Delchet, L.; Breunig, S.
A New Generation of Silicone Antifoams with Improved Persistence ........................................... 700
Huggins, A; Chugg, K ; Roos, C.; Nienstedt, S.
Silicone Mist Supressors for Fast Paper Coating Processes ............................................................ 704
Delis, J.; Kilgour, J.
Silicone Copolymers for Coatings, Cosmetics, and Textile and Fabric Care .................................. 710
Stark, K.
Silicone-Based Copolymers for Textile Finishing Purposes - General Structure Concepts,
Application Aspects, and Behavior on Fiber Surfaces .................................................................... 716
Lange, H.; Wagner, R.; Hesse, A.; fioss, H.; Hocker, H.
Silanes as Efficient Additives for Resins ......................................................................................... 722
van Herwijnen, H. W. G.; Kowatsch, S.; Wagner, R. A.
New UV-Curable Alkoxysiloxanes Modified with Tris(trimethylsily1)methyl Derivatives ........... 729
Kowalewsh, A.; Stancvk, W. A.
New Methacrylic Silanes: Versatile Polymer Building Blocks and Surface Modifiers .................. 734
Pfzfer, J.
Hydrolysis Studies of Silane Crosslinkers in Latexes ..................................................................... 741
Cooke, J. A.; Cai, W.; Lejeune, A.
Mastering Crosslinking in Silicone Sealants ................................................................................... 750
Pujol, J.- M; Frangois, J.- hi;D albe, B.
Selecting the Right Aminosilane Adhesion Promoter for Hybrid Sealants ..................................... 757
Mack, H.
Isocyanatomethyl-DimethylmonomethoxyS ilane: A Buildung Block for RTV-2 Systems ...........7 65
Ziche, W.
The Influence of Different Stresses on the Hydrophobicity and the Electrical Behavior of
Silicone Rubber Surfaces ................................................................................................................. 770
Barsch, R.; Jahn, H.; Steinberger, H ; Friebe, R.
Silicone Magnetoelastic Composite ................................................................................................. 779
Stepanov, G. V.; Alekseeva, E. I.; Gorbunov, A. L; Nikitin, L. V.
Modifiers for Compounded Rubbers Based on Fluoro- and Phenylsiloxane Rubbers .................... 785
Ryzhova, 0. G.; Korolkova, T. N.; Kholod, S. A!
Polyphenylsilsesquioxane-Polydiorganosiloxane Block Copolymers ........................................... .792
Semenkova, N Yr.; Nanushyan, S, R.; Storozenko, P. A.
Thermoplastic Silicone Elastomers .................................................................................................. 796
Schayer, 0.; Weis, J.; Delica, S.; Csellich, F.; Kneipl, A.
Contents XVII
Silicone Hybrid Copolymers - Structure, Properties, and Characterization .................................. 802
Hiller, W.; Keller, W.
Hydrolytic Stability o f Silicone Polyether Copolymers .................................................................. 807
Pigeon, M G.; Czech, A. M ; Landon, S. J.
Silane-Crosslinking High-Performance Spray Foams ..................................................................... 8 13
Poggenklas, B.; Sommer, H.; Stanjek, K: Weidner, R.; Weis, J.
Phase Behavior of Short-Chain PDMS-b-PEO Diblock Copolymers and Their Use as
Templates in the Preparation of Lamellar Silicate Materials ........................................................... 8 18
Kickelbick, G.; Hiising, N
Nanoscale Networks for Masonry Protection .................................................................................. 825
Lork, A.; Sandmeyer, F.; Kohler, J.; Weis, J.
Chapter VI
Silicon-Based Materials
Mesostructured Silica and Organically Functionalized Silica - Status and Perspectives ............. 860
Schiith, F.; Wang, Y.; Yang, C.-M; Zibrowius, B.
Physical-Chemical Features of Synthetic Amorphous Silicas and Related Hazard and Risk
Assessment ....................................................................................................................................... 869
Heinemann, M ; Bosch, A.; Stintz, M.; Vogelsberger, W.
Particle Size of Fumed Silica: a Virtual Model to Describe Fractal Aggregates ............................. 875
Batz-Sohn, C.
Characterization of Size and Structure of Fumed Silica Particles in Suspensions .......................... 882
Babick, F.; Stintz, M.; Barthel, H.; Heinemann, M
Adsorption of Water on Fumed Silica ............................................................................................. 888
Brendlk, E.; Ozil, F.; Balard, H.; Barthel, H
Methylene Chloride Adsorption on Pyrogenic Silica Surfaces ....................................................... 895
Brendlk, E.; Ozil, F.; Balard, H.; Barthel, H.
Pyrogenic Silica - Mechanisms of Rheology Control in Polar Resins .......................................... 902
Gottschalk-Gaudig, T. ; Barthel, H
Silica Adhesion on Toner Surfaces Studied by Scanning Force Microscopy (SFM) ...................... 910
Heinemann, M ; Voelkel, U.; Barthel, H.; HiId S.
Characterization of Silica-Polymer Interactions on the Microscopic Scale Using Scanning
Force Microscopy ............................................................................................................................ 920
Konig, S.; Hild, S.
Advanced Hydrophobic Precipitated Silicas for Silicone Elastomers ............................................. 927
Kawamoto, K.; Panz, C.
Iodine Insertion into Pure Silica Hosts with Large Pores ................................................................ 930
Nechifor, R.; Behrens, P.
X V I I I Contents
Metal-Doped Silica Nano- and Microsized Tubular Structures ....................................................... 937
Milbrudt, M.; Mursmunn, H. C.; Greulich- Weber, S.
Branched Functionalized Polysiloxane-Silica Hybrids for Immobilization of Catalyst ................. 942
Rbzga-Wijus, K.; Chojnowski, J.; Fortuniuk, K; Scibiorek, M
Investigations into the Kinetics of the Polyamine-Silica System and Its Relevance to
Biomineralization ............................................................................................................................. 948
Barnreuther, P.; Jahns, M ; Krueger, I.; Behrens, P.; Horstmann, S.; Menzel, H.
Polyol-Modified Silanes as Precursors for Mesostructured Silica Monoliths ................................. 955
Hiising, N.; Brundhuber, D.; Torma, K; Ruub, C.; Peterlik, H.
Self-organized Bridged Silsesquioxanes ......................................................................................... 962
Moreau, J. J. E.; Vellutini, L.; Wong Chi Man, M ; Bied, C.
Carbamatosil Nanocomposites with Tonic Liquid: Redox Electrolytes for Electrooptic Devices ... 967
Jovanovski, V.; Orel, B.; surca Vuk, A.
Silicone Nanospheres for Polymer and Coating Applications ......................................................... 977
Ebenhoch, J.; Oswuldbuuer, H.
New Approaches and Characterization Methods of Functional Silicon-Based
Non-Oxidic Ceramics ...................................................................................................................... 981
Haberecht, J.; Krumeich, F.; Hametner, K; anther, D.; Nesper, R.
Weinmunn, M.; Horz, M.; Muller, A.; Aldinger, F.
Ushakov, N. K; Finkelshtein, E. Sh.; Krusheninnikov, E. G.
Chemical Functionalization of Titanium Surfaces .......................................................................... 999
Cossement, D.; Mekhulij Z.; Delhalle, J.; Hevesi, L.
Documentation of Silicones for Chemistry Education and Public Understanding ........................ 1006
Tuusch, M W.
Preceramic Polymers for High-Temperature Si-B-C-N Ceramics ................................................ 987
Heterochain Polycarbosilane Elastomers as Promising Membrane Materials ................................. 994
Author Index .................................................................................................................................. 1009
Subject Index .................................................................................................................................. 1015

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